Just what toxic compounds have you read cast iron releases? I have heard it releases iron, which can or can not be good, bepending on the iron needs of the person, but in all I have heard nothing bad about cast iron. The information regarding teflon was very upsetting to say the least.
I try to keep it simple regarding food preparation and use time tested methods . I have cast iron, stainless steel, glass and terracotta.
One of my favorite cooking tools is my tajine. You cook on a very low flame for hours. The vapor circulates up the chimney and down again to the food being prepared. The results are spectacular (of the mechanics of proper use of the tajine, not my cooking), however it is rather time consuming. All the flavors melt together into a nice thick sauce.
Some substitute dutch ovens for a real tajine, but in my opinion, from experience, there is no comparison to the difference in flavor.
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