1. Güzel bir günbatımı görmek istiyorum.
2. Güzel bir günbatımı görmeyi istiyorum.
The first sentence sounds strange as seeing a sunset is not the same kind of action as seeing a film, reading a book or eating a dinner. It feels like when you say "Güzel bir günbatımı görmek istiyorum" you are expecting somebody to appear and say "Yes, Sir. Just a second please. Would you like anything else with the sunset" It is like saying "Let's arrange things in such a way that I can see a nice sunset".
A movie director could say "güzel bir günbatımı görmek istiyorum" if somebody has control over the sunset with some technical light effects or such or if they are talking of the sunset in the film which is changeable in computer environment. "Show me a nice sunset here and remove these birds in the sky. Make the red a little darker. I want to see a nice sunset here."
"Günbatımını görmek istiyorum" would be a strong sentence. It has the accusative case so "I want to see THE sunset" where the sunset is the direct object I'm referring to. It is clear which sunset I want to see. But we can't use this in 1 or 2 since "güzel bir", "a nice" is implying that it is undefinitive and I'm not interested which sunset it is but just it has to be nice.
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